People around the globe have protected their skin using a variety of substances throughout history. In the 19th and 20th centuries, deeper understanding of sunlight and the way it affects skin led to more protective sunscreen formulations.
Research:

Gustave Flaubert and the ‘Madame Bovary’ Trial
45:15

Elizabeth Bisland, Beyond the Trip Around the World
42:54

SYMHC Classics: Marie Laurencin
32:46