People around the globe have protected their skin using a variety of substances throughout history. In the 19th and 20th centuries, deeper understanding of sunlight and the way it affects skin led to more protective sunscreen formulations.
Research:

Behind the Scenes Minis: Piece of Work
17:48

E. Virgil Neal: Hypnotist, Fraudster, Tycoon, Part 2
41:22

E. Virgil Neal: Hypnotist, Fraudster, Tycoon - Part 1
35:28