People around the globe have protected their skin using a variety of substances throughout history. In the 19th and 20th centuries, deeper understanding of sunlight and the way it affects skin led to more protective sunscreen formulations.
Research:

Embroidery History Sampler, Part 1
36:00

SYMHC Classics: Paul Cuffe
30:49

Behind the Scenes Minis: This Monkey’s Gone to Heaven
19:22